Electrochemical characteristics of the dynamic progression of erosion-corrosion under different flow conditions and their effects on corrosion rate calculation

Journal of Solid State Electrochemistry - The erosion-corrosion performance of X65 carbon steel at different flow conditions was electrochemically studied. Results show that the anodic polarization...     

Molecular-Based Design of Microporous Carbon Nanosheets

Microporous carbons afford high surface areas, large pore volumes, and good conductivity, and are fascinating over a wide range of applications. Traditionally synthesized microporous carbon materials usually suffer from some limitations, such as poor accessibility and slow mass transport of molecules due to the micrometer-scale diffusion pathways and space confinement imposed by small pore sizes. Two-dimensional microporous carbon materials, denoted as microporous carbon nanosheets (MCNs), possess nanoscale thickness, which allows fast mass and heat transport along the z axis; thus overcoming the drawbacks of their bulk counterparts. Herein, recent breakthroughs in the synthetic strategies for MCNs are summarized. Three typical methods are discussed in detail with several examples: pyrolysis of organic precursors with 2D units, a templating method that uses wet chemistry, and the molten salt method. Among them, molecular-based assembly of MCNs in the liquid phase shows more controllable morphology, thickness, and pore size distribution. Finally, challenges in this research area are discussed to inspire future explorations.     

棒状LiZnPO4的低温合成与表征

LiZnPO₄的性能与其形貌密切相关,其合成常用的固相法和水热法均无控制其微观形貌的优势。 本文采用改进的沉淀法成功合成了具有棒状结构的LiZnPO₄。 利用热重-差热分析仪(TG-DSC)、X射线衍射仪(XRD)、傅里叶变换红外光谱(FTIR)以及场发射扫描电子显微镜(FE-SEM)等技术研究了LiZnPO₄形成过程、晶相组成、微观结构和形貌。 同时探究了合成方法、煅烧温度、煅烧时间、酸的种类对LiZnPO₄形貌的影响。 结果表明,相比较于固相法,以醋酸为原料的改进沉淀法不仅可以有效降低LiZnPO₄的合成温度至500 ℃,而且很容易控制棒状LiZnPO₄的形成。 在600 ℃下煅烧2 h后可以获得分散性良好、横截面为矩形、直径约为2 μm的规则棒状LiZnPO₄。 此外,对比颗粒状LiZnPO₄和棒状LiZnPO₄的光响应能力,发现棒状LiZnPO₄的光响应能力明显增强。     

平头锥型回转体高速入水结构强度数值分析

为探究回转体在高速入水过程中的结构强度，基于非线性有限元LS-DYNA软件中流固耦合任意拉格朗日-欧拉(arbitrary Lagrangian-Eulerian, ALE)方法，分析了不同壁厚的回转体以100 m/s的初速度入水过程中的冲击力特性和结构强度。结果表明:数值计算得到的入水冲击压强峰值和速度衰减曲线与相应的理论值吻合较好，从而验证了数值方法的有效性；入水冲击载荷峰值出现在结构入水瞬间，结构入水后冲击载荷急剧变小且微小震荡；回转体的结构形式对其在高速入水过程中的结构强度有重要影响，尤其回转体头部厚度影响回转体结构强度，当回转体头部厚度为8 mm、后体壁厚大于2.5 mm时，可以保证回转体强度要求。     

Synthesis and application of near-infrared absorbing morpholino-containing aza-BODIPYs

Morpholino-containing aza-BODIPYs at 3,5-positions were synthesized. The maxima absorption and emission of these dyes locate at the near-infrared region. Aza-BODIPY 1 with the morpholino group as a pH-sensitive functionality could be used to be a pH probe, and the dramatic increase in fluorescence intensity at 675 nm by about 1500 folds. Moreover, the singlet oxygen generation of PS 2 with the dibromo groups at 2,6-positions was more effective than that of the parent dye 1.     

Property and evolution of the running-in attractor in an actual dynamic system

In this paper, the issue of adaptive neural tracking control for uncertain switched multi-input multi-output (MIMO) nonstrict-feedback nonlinear systems with average dwell time is studied. The system under consideration includes unknown dead-zone inputs and output constraints. The uncertain nonlinear functions are identified via neural networks. Also, neural networks-based switched observer is constructed to approximate all unmeasurable states. By means of the information for dead-zone slopes and barrier Lyapunov function (BLF), the problems of dead-zone inputs and output constraints are tackled. Furthermore, dynamic surface control (DSC) scheme is employed to ensure that the computation burden is greatly reduced. Then, an observer-based adaptive neural control strategy is developed on the basis of backstepping technique and multiple Lyapunov functions approach. Under the designed controller, all the signals existing in switched closed-loop system are bounded, and system outputs can track the target trajectories within small bounded errors. Finally, the feasibility of the presented control algorithm is proved via simulation results.

     

单斜ZnP2负极材料的锂化机理及性能

过渡金属磷化物电位低且比容量高, 是有发展前景的锂离子电池(LIBs)负极材料. 其中, ZnP₂属于双活性负极材料, Zn与P都能与Li⁺发生反应, 储Li⁺性能更具有竞争力. 但是, 对于ZnP₂的锂化机理及产物尚不明确. 采用第一性原理计算和电化学测试方法研究了ZnP₂的电子性质和电化学性能, 通过理论计算和实验测试相结合阐述了ZnP₂的锂化机制. 首先, 以密度泛函理论(DFT)计算揭示了ZnP₂的锂化机理、Li⁺扩散路径、势垒和理论比容量(1477 mAh/g). 其次, 通过直流电弧等离子体法及固相烧结法合成ZnP₂, 并测试其首圈放电曲线, 显示放电容量为1439 mAh/g, 与理论计算结果相近. 此外, 薄膜X射线衍射(XRD)检测最终产物成分为LiZn和Li₃P, 与DFT计算结果一致.     

Dynamic analysis and regulation of the flexible pipe conveying fluid with a hard-magnetic soft segment

Applied Mathematics and Mechanics - The recently developed hard-magnetic soft (HMS) materials can play a significant role in the actuation and control of medical devices, soft robots, flexible...     

Computation of hydrodynamic mass and damping coefficients for a cavitating marine propeller flow using a panel method

The present paper deals with the numerical calculation of hydrodynamic mass and damping coefficients under consideration of unsteady sheet cavitation on marine propeller flows. In the first part of the paper, the mathematical and numerical background behind the numerical method is introduced. The numerical calculations carried out in this work are based on a low-order panel method. Panel methods belong to the class of collocation techniques and are applied to obtain a numerical solution of a potential flow based system of boundary integral equations. They are suitable for the present application because of their short computation time which makes them applicable in the design process of marine propellers.Additionally, two different approaches for the determination of hydrodynamic masses and damping are introduced in this work. The hydrodynamic masses and damping are important in studies of the ship motion in seaway and in the analysis of vibrations of a vessel and its appendages. The developed approaches are applied on a propeller flow in heave motion. Hereby, the calculations are performed for a non-rotating and rotating propeller under non-cavitating and cavitating conditions. The results obtained from the simulations are discussed in detail and an outlook is given.